Introduction to spectroscopy
Introduction to spectroscopy: part 1
The interaction between matter and radiation can be analyzed through spectroscopy.
Radiation: basically
radiation is energy transferred by electromagnetic waves. It includes x rays, gamma rays, visible light... etc.
Properties of electromagnetic waves:
v All electromagnetic waves travel at the
same speed (C)
v Wave length: ( λ) the length of one complete cycle
v Amplitude: (A) Half of the perpendicular
height between a trough and a crest
v Frequency: (Hz) The number of cycles per seconds
v Wave number: ( ν) The number of wavelengths that occupy
per 1cm
Wave Theory:
C
= λ. V
Particle Theory:
Quantum numbers:
All energy levels are quantized.Because the energy levels are discrete, transition between energy states only occur when certain energy is absorbed.
There are several transitions that can be investigated such as electronic transition, vibrational transition and rotational transition.
The total energy of a molecule can be written as
ET
= Eelec + Evib +Erot+ Etrans
introduction to spectroscopy: part 2 (rotational spectroscopy)
Introduction to spectroscopy: part 3 (Vibrational Spectroscopy)
Introduction to spectroscopy: part 3 (Vibrational Spectroscopy)
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